
pH is a measure of how acidic or basic water is, with the pH scale ranging from 0 to 14, 7 being neutral. pH plays a crucial role in environmental pollution, as it is linked to anthropogenic acidification and its environmental effects, such as coral and forest death. For instance, acid rain, caused by the reaction of water with nitrogen oxides, sulfur oxides, and other acidic compounds, can lower the pH of water bodies, leading to increased solubility and toxicity of metals and nutrients, which can harm aquatic plants and animals. On the other hand, high pH can cause metals to precipitate and make chemicals like ammonia toxic to aquatic life. Additionally, pH can influence the lives of bacteria and the availability of contaminants in water.
What You'll Learn
Acid rain
The main sources of these acidic compounds are anthropogenic, such as mining and smelting operations, and fossil fuel combustion. However, nitrogen oxides can also be produced naturally by lightning strikes, and sulfur dioxide is produced by volcanic eruptions. Acid rain was first systematically studied in Europe in the 1960s, and in the United States and Canada in the 1970s. Since then, governments in Europe and North America have made efforts to reduce the release of sulfur dioxide and nitrogen oxide into the atmosphere through air pollution regulations.
The effects of acid rain are widespread and detrimental. In natural environments, it lowers the biological productivity of lakes, reducing the amount of forage fish available. It also damages forest ecosystems by draining nutrients from the soil and adversely affecting tree growth. Acid rain also causes paint to peel, corrosion of steel structures, and weathering of stone buildings and statues. Additionally, the pollutants that cause acid rain can be harmful to human health, as they can enter the lungs and cause lung disease, heart attacks, and difficulties for people with asthma.
The pH of water sources can be affected by acid rain, with poorly buffered water sources being particularly vulnerable to decreased pH through runoff. Limestone quarries, for example, have higher pH levels due to the presence of carbonate materials in the stone, which can help to limit pH changes due to acid rain. Intense photosynthesis also increases the pH of water as it removes CO2.
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Industrial wastewater
The pH of a water body is a measure of how acidic or alkaline it is. The pH scale ranges from 0 to 14, with 7 being neutral. pH values less than 7 are acidic, while pH values greater than 7 are alkaline or basic. A changing pH in a stream can be an indicator of increasing pollution or some other environmental factor.
High pH in water can be caused by discharges from industries that use lime, lye, or sodium hydroxide (NaOH). For instance, cement, asphalt, and soap manufacturing may be sources of high pH due to the use of lime or lye. Industrial effluents, if not properly treated, can be discharged at a low pH.
High pH in industrial wastewater can have several negative consequences. Firstly, it can cause water pipes and water-using appliances to become encrusted with deposits. It can also reduce the effectiveness of chlorine disinfection, requiring the use of additional chlorine. Furthermore, high pH can affect the solubility of heavy metals, which are commonly found in industrial wastewater, particularly from mining industries.
To comply with environmental regulations, many industrial facilities install pH neutralization systems to treat their wastewater before discharge. These systems can be integrated into existing machinery or implemented as part of a new, complete system. pH adjustment in wastewater treatment is often necessary to precipitate out contaminants such as emulsified solids, oils, soaps, surfactants, or dissolved metals.
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Effects on aquatic life
High pH in water bodies can have detrimental effects on aquatic life. Firstly, it can cause stress in aquatic organisms, reducing their hatching and survival rates. The further the pH deviates from the optimum range, the higher the mortality rates, particularly in more pH-sensitive species.
High pH levels can also damage the gills and skin of aquatic organisms, leading to death, especially at levels exceeding 10.0. Certain African cichlids can withstand high pH levels of up to 9.5, but most fish cannot. Even at typical pH levels of 9.0, the presence of ammonia in the water can be fatal. As pH increases, the concentration of toxic unionized ammonia (NH3) rises, leading to increased mortality rates among aquatic organisms.
The effects of high pH on aquatic life also extend to the ecosystem. As pH levels rise, the solubility of phosphorus and other nutrients increases, promoting excessive growth of aquatic plants and algae. This, in turn, increases the demand for dissolved oxygen, creating a stressful environment for other organisms in the water, even if pH levels remain within the optimum range.
Additionally, high pH levels can cause the invasion of mosses in water bodies as pH falls below 5.0. This can disrupt the natural balance of the ecosystem and have further implications for aquatic life.
It is worth noting that while some water bodies with high pH levels, such as Lake Natron, can support thriving ecosystems, they may also preserve the bodies of animals that died due to the high pH. The presence of sodium carbonate in Lake Natron, for example, mummifies animals, similar to ancient Egyptian mummification.
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Human health impact
The human body works constantly to maintain the right pH levels in the blood and other fluids, as this is essential for good health. The body's pH balance is also called the acid-base or acid-alkaline balance. The pH scale ranges from 0 to 14, with 7 being neutral, like pure water. A pH below 7 is acidic, and a pH above 7 is alkaline or basic.
Blood is naturally slightly alkaline, with a normal pH range that is slightly basic, between 7.35 and 7.45. A drop in blood pH below 7.35 is a condition called acidosis, where the blood becomes too acidic. Alkalosis is the condition where blood pH rises above 7.45, making the blood too alkaline. These conditions can be caused by lung or kidney conditions, or by dietary factors.
The lungs and kidneys are the two main organs that help balance blood pH. The lungs remove carbon dioxide through breathing, while the kidneys remove acids through urine or excretion.
Studies have shown that the pH of drinking water can affect the composition of the gut microbiota and host glucose regulation in humans. A study on the effects of bicarbonate-rich mineral water, which tends to have a higher pH, showed a significant decrease in glycoalbumin and an increase in the relative abundance of certain gut bacteria. Another study on the effects of coffee consumption found that it altered the gut microbiota composition and increased gastric acid secretion.
While the impact of drinking water pH on human health is still being studied, it is clear that maintaining the right pH levels in the body is crucial for overall health and wellbeing.
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Natural pH variation
The pH scale measures how acidic or basic an object is, with values ranging from zero (most acidic) to 14 (most basic). Pure water has a pH of 7, which is considered neutral. pH levels below 7 are acidic, while those above 7 are basic or alkaline.
The pH of water bodies can also be influenced by natural precipitation, such as rain and snow, which typically have a pH of around 5.6 due to contact with carbon dioxide and other atmospheric influences. This slightly acidic rain can benefit carbonate soils by providing essential nutrients. Intense photosynthesis can increase the pH of water as it removes carbon dioxide, although these changes are usually short-lived.
Additionally, pH levels can fluctuate daily due to natural processes such as photosynthesis, respiration, and decomposition, which influence carbon dioxide levels in the water. The degree of change depends on the alkalinity of the water, with noticeable diurnal variations.
It is important to note that while natural pH variation occurs, human activities can exacerbate these changes and lead to environmental issues such as anthropogenic acidification, as mentioned in the provided source.
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Frequently asked questions
pH stands for "power of hydrogen" and is a logarithmic scale that measures how acidic or basic water is. Solutions with a pH less than 7 are generally referred to as acidic, while those with a pH greater than 7 are basic or alkaline.
pH can alter the chemical state of many pollutants, changing their solubility, transport, and bioavailability. This can increase the exposure to and toxicity of metals and nutrients to aquatic plants and animals.
At very high pH, metals tend to precipitate, and chemicals such as ammonia become toxic to aquatic life. The water tends to have an unpleasant smell and taste in alkaline conditions.
Streams and lakes with low buffering capacity or low flow are particularly susceptible to low pH from acidic deposition. Acidic deposition has occurred in the northeastern United States due to emissions from cities and industrial plants.
Human activities such as mining, fossil fuel combustion, and agricultural runoff can contribute to acid rain and acidic groundwater seepage, impacting the pH of water bodies and causing environmental pollution.