
Cyanide pollution is a serious issue that can have detrimental effects on human health and the environment. Cyanide is an inorganic chemical compound with a variety of natural and anthropogenic sources. Natural sources include certain plant foods, such as almonds, cassava roots, and apricot kernels, while anthropogenic sources include industrial activities such as mining, plastic production, and vehicle exhaust emissions. Exposure to cyanide can occur through inhalation, ingestion, or skin and eye contact, leading to severe health effects and even death. Understanding the sources of cyanide pollution is crucial for mitigating its impacts and ensuring the safety of both human and environmental ecosystems.
| Characteristics | Values |
|---|---|
| Cyanide pollution sources | Industrial processes, natural sources, intentional acts |
| Industrial sources | Mining, metallurgy, chemical industries, plastic production, vehicle exhaust, waste burning, pesticides |
| Natural sources | Certain plant foods, fruit pits and seeds, bamboo, tobacco smoke |
| Intentional acts | Terrorism, chemical warfare |
| Effects on humans | Lethal in high doses, prevents cells from using oxygen, affects the heart, respiratory and nervous systems |
| Treatment | Move to fresh air, oxygen therapy, antidotes (sodium nitrite, sodium thiosulfate) |
| Prevention | Wear respirators, avoid skin and eye contact, wash exposed areas, remove contaminated clothing |
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What You'll Learn

Industrial processes
Cyanide pollution can be attributed to several industrial processes, including mining, galvanic, and chemical industries. Here are some specific examples of how cyanide pollution can be generated through these activities:
- Mining Industry: The mining industry is a significant source of cyanide pollution, particularly in gold and silver mining operations. Cyanide compounds are often used in the extraction of these precious metals, and improper handling or disposal of cyanide-containing residues can lead to environmental contamination. For instance, gold mining operations produce cyanide residues that, if not properly managed, can pollute water sources.
- Chemical Industries: Various chemical industries utilize hydrogen cyanide and cyanides in their processes. This includes the production of plastics, dyes, and certain chemicals. The release of untreated or partially treated wastewater from these industries can introduce cyanide ions into the environment, contaminating water bodies and affecting aquatic life.
- Wastewater Treatment: While wastewater treatment facilities are designed to remove contaminants, they can also inadvertently produce cyanide compounds during the treatment process. For example, during water chlorination, low levels of cyanogen chloride may be generated. If the treatment process is not adequately controlled, these compounds can be released back into the environment.
- Metal Production: The production of iron and steel involves various chemical processes that can generate cyanide compounds as by-products. For instance, the integrated ozonation-assisted electrocoagulation process used in the steel industry can produce cyanide-containing wastewater.
- Industrial Fires: Fires at industrial workshops and plants can release cyanide compounds into the environment. The combustion of certain materials or chemicals containing cyanide can result in the formation of toxic cyanide gases and particles, which can then be released into the atmosphere during a fire.
- Tobacco Smoke: While not a direct industrial process, the tobacco industry contributes to cyanide pollution through the production and consumption of tobacco products. Tobacco smoke contains cyanide ions, which are released into the environment during smoking. This can affect not only the smoker but also those exposed to secondhand smoke.
The impact of cyanide pollution from these industrial processes is significant, and proper waste management, treatment technologies, and regulatory measures are crucial to mitigate their environmental and health effects.
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Wastewater treatment facilities
Cyanide pollution in wastewater can occur due to various industrial processes, including metal cleaning, plating, electroplating, metal processing, automobile parts manufacturing, steel tempering, mining, photography, pharmaceuticals, coal coking, ore leaching, and plastics. These industries can discharge wastewater containing cyanide, which then requires treatment to prevent environmental contamination.
In addition to biological treatments, physicochemical methods are also employed. These methods avoid generating toxic by-products but do not eliminate contaminants from their original source. Instead, they transfer pollutants to another medium for further treatment. Adsorption processes, for example, are cost-effective and highly efficient in treating cyanide wastewater. However, they only transfer the cyanide to an adsorbent or substrate rather than removing it from the wastewater.
Electrochemical techniques, such as direct and indirect electrooxidation, are effective in treating high concentrations of cyanide in wastewater. Direct electrooxidation oxidizes cyanide at the anode while reducing heavy metals at the cathode. On the other hand, indirect oxidation uses a "non-active" anode to generate strong oxidizing species, facilitating cyanide oxidation. While electrochemical techniques generate fewer harmful by-products, they have the limitation of high energy consumption, especially on a large scale.
Chemical oxidation methods, such as alkaline chlorination and hydrogen peroxide degradation, are historically used to treat cyanide wastewater. However, these methods have been largely replaced by more efficient, less polluting, and cost-effective approaches. Enzymatic treatment, for example, utilizes enzymes as versatile catalysts for waste/pollutant treatment processes, offering advantages over conventional treatments.
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Vehicle exhaust
Cyanide pollution is a serious issue that can have detrimental effects on the environment and human health. One significant source of cyanide pollution is vehicle exhaust, which releases hydrogen cyanide (HCN) into the atmosphere. Motor vehicle exhaust emissions have been found to contain HCN, posing potential health risks to the public.
One study focused on light-duty motor vehicles operating at idle, as these conditions pose the highest risk of exposure, particularly in enclosed spaces. The results showed that HCN was detected in 89% of the sampled exhaust streams. Interestingly, there was no correlation between HCN emissions and the instantaneous air-fuel ratio or any single co-emitted pollutant. However, a moderate correlation was observed between HCN emissions and the product of carbon monoxide and nitric oxide emissions during cold-start conditions.
The emission factors for HCN from different types of vehicles were also investigated. The study found that gasoline vehicles had the highest emissions of HCN, while biodiesel fuel showed potential for significantly reducing HCN emissions. These findings highlight the importance of considering fuel type in mitigating cyanide pollution from vehicle exhaust.
In addition to laboratory studies, ambient measurements of HCN in traffic-dominated areas have further confirmed the impact of vehicle emissions. Measurements in Toronto, Canada, for example, indicated that vehicle emissions of HCN are the dominant source of exposure in urban regions. This underscores the need for ongoing research and the development of strategies to reduce cyanide pollution from vehicle exhaust, particularly in densely populated areas.
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Natural sources
Cyanide is a fast-acting poison that can be lethal. It exists in the environment in many different forms and can be found in nature at low levels. Cyanide is produced by certain bacteria, fungi, and algae. It is also found in cigarette smoke, vehicle exhaust, and some foods.
In a natural environment, cyanide exists as cyanogenic glycosides in plant seeds. Cyanogenic glycosides can be found in apricot kernels, cassava roots, bamboo shoots, millet sprouts, almonds, lima beans, spinach, soy, and tapioca. Cyanide is also found in fruit pits, which can be dangerous to children who accidentally eat them. The cyanide in these foods is part of sugars or other naturally occurring compounds. However, it is important to note that the edible parts of plants that are commonly consumed in the United States, such as tapioca, contain relatively low amounts of cyanide.
Natural processes, such as the biogenic processes of higher plant bacteria and fungi, also release cyanide into the air, water, and soil. The concentration of hydrogen cyanide in unpolluted air is typically less than 0.2 parts per million (ppm). The cyanide in the air is mainly in the form of gaseous hydrogen cyanide, with a small amount present as fine dust particles. Rain and snow help remove cyanide particles from the air, but gaseous hydrogen cyanide is more challenging to eliminate.
Vitamin B12, a natural chemical containing cyanide, is beneficial for preventing anemia. The body can also convert small amounts of cyanide into thiocyanate, a less harmful substance that is excreted in urine. These natural processes help mitigate the potential harmful effects of cyanide exposure.
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Mining
Cyanide is a rapidly acting, potentially deadly chemical. It is often used in the mining industry to extract gold and other precious metals from low-grade ores. The process, known as gold cyanidation or the cyanide process, involves suspending crushed ore in a cyanide solution to dissolve the desired metals. While this process is effective and cheap, it is also highly toxic and has led to environmental and health disasters.
One of the most well-known incidents of cyanide pollution from mining occurred in 1982 at the Zortman-Landusky Mine in Montana, USA. Over 52,000 gallons of cyanide solution leaked from the mine, poisoning the aquifer that supplied fresh drinking water to the nearby town of Zortman. This resulted in long-term contamination of the water supply, which continued to affect neighbouring streams even after the mine closed.
Another incident occurred at Glencairn's Bellavista gold mine in Costa Rica, where structural failure led to the release of cyanide from a heap leach pile. Heap leaching is a common practice in gold mining, where a cyanide solution is sprayed over large heaps of crushed ore. While this method is more controlled than some others, reducing the risk of spills, the waste (known as tailings) is often stored behind large dams that can fail catastrophically.
The highly toxic nature of cyanide has led to controversy over its use in mining, with some places choosing to ban it. Despite industry claims that cyanide is relatively safe and breaks down rapidly in water, its compounds can persist and cause harm. For example, cyanide spills can contaminate groundwater and neighbouring streams, leading to adverse effects on aquatic life, including fish and migratory birds, as well as terrestrial wildlife and vegetation.
To mitigate these risks, the European Parliament and Council adopted Directive 2006/21/EC after the 2000 Baia Mare cyanide spill. This directive sets limits on the concentration of cyanide in waste from extractive industries and requires companies to put in place financial guarantees for post-mining clean-up operations. The industry has also voluntarily adopted a "Cyanide Code" to reduce environmental impacts through third-party audits.
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Frequently asked questions
Cyanide occurs naturally in certain plant foods, including almonds, millet sprouts, lima beans, soy, spinach, bamboo shoots, apricot kernels, and cassava roots.
Cyanide enters the environment mainly through wastewater. It can also enter the environment as a result of fires at industrial workshops and houses, from vehicle exhaust, and from tobacco smoke.
The major sources of cyanide in water are discharges from some metal mining processes, organic chemical industries, iron and steel plants, and publicly owned wastewater treatment facilities.
Cyanide prevents cells from using oxygen, and eventually, these cells die. The heart, respiratory system, and central nervous system are most susceptible to cyanide poisoning.
Symptoms of cyanide exposure can include breathing in cyanide gas, swallowing solid or liquid cyanide, skin or eye contact, and drinking water containing cyanide.




















