Air Pollutants: What's In The Air We Breathe?

what substances are present in polluted air

Air pollution is a pressing issue that poses severe health risks to humans and the planet. Polluted air contains various harmful substances, known as air pollutants, which alter the natural composition of the atmosphere. These pollutants can be primary or secondary. Primary pollutants are emitted directly from sources such as vehicle combustion, industrial emissions, and forest fires. Secondary pollutants arise from chemical reactions between primary pollutants and other atmospheric constituents. The most common and harmful air pollutants include particle pollution, carbon dioxide, mercury, lead, dioxins, benzene, nitrogen oxides, sulfur oxides, and volatile organic compounds (VOCs). These substances contribute to respiratory and cardiovascular diseases, cancer, ecosystem degradation, and climate change.

Characteristics Values
Particulate matter PM10 and PM2.5
Composition of particulate matter Sulphate, nitrates, ammonia, sodium chloride, black carbon, mineral dust, water, pollen, sea spray, wind-blown dust from erosion, agricultural spaces, roadways, and mining operations
Effects of particulate matter Irritation of eyes, nose, and throat, cardiovascular issues, cerebrovascular issues, respiratory issues, adverse perinatal outcomes, and lung cancer
Gases Carbon monoxide, nitrogen dioxide, sulfur dioxide, carbon dioxide, and volatile organic compounds
Other pollutants Smog, soot, lead, mercury, dioxins, benzene

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Greenhouse gases, e.g. carbon dioxide, contribute to global warming

Air pollution refers to the release of pollutants into the air, which are detrimental to human health and the planet as a whole. Some common air pollutants include mercury, lead, dioxins, benzene, ground-level ozone, carbon monoxide, nitrogen oxides, sulfur oxides, and particle pollution.

Greenhouse gases, such as carbon dioxide (CO2), are among the top air pollutants affecting the planet and human health. While greenhouse gases naturally occur in the atmosphere and are crucial for keeping the planet at a habitable temperature, human activities have significantly increased their concentrations. The burning of fossil fuels, such as driving cars, heating homes, and running power plants, releases large amounts of CO2 into the atmosphere. Since the Industrial Revolution, carbon dioxide levels have risen drastically and are now substantially higher than at any time in the last 750,000 years.

The concentration of CO2 in the atmosphere has increased from approximately 280 parts per million (ppm) in pre-industrial times to over 400 ppm in 2018, a 40% increase. This rate of increase is expected to lead to concentrations exceeding 900 ppm by the end of the 21st century. The release of CO2 and other greenhouse gases contributes to the greenhouse effect, which warms the Earth's surface and lower atmosphere.

Greenhouse gases act like the glass in a greenhouse, absorbing and trapping the sun's heat in the atmosphere instead of letting it escape into space. This enhances the natural greenhouse effect, leading to global warming and climate change. The Northern Hemisphere has warmed more than the Southern Hemisphere, with some regions experiencing temperature rises of more than 5°C.

In addition to carbon dioxide, other greenhouse gases include methane (CH4), nitrous oxide (N2O), and fluorinated gases (F-gases). F-gases, such as hydrofluorocarbons (HFCs) and sulfur hexafluoride (SF6), are synthetic and have a much stronger warming effect than CO2, even when emitted in smaller quantities. To combat global warming, the EU has set targets to reduce greenhouse gas emissions by 55% by 2030 and reach net-zero emissions by 2050.

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Fossil fuels release harmful chemicals and gases, e.g. carbon monoxide

Fossil fuels, such as coal, oil, and natural gas, are major contributors to air pollution. When these fuels are burned, they release harmful chemicals and gases, including carbon monoxide, nitrogen oxide, and particulate matter, which have detrimental effects on both human health and the environment.

Carbon monoxide (CO) is a colourless, odourless, and toxic gas that is harmful to humans even in small amounts. It is produced during the incomplete combustion of fossil fuels, such as in car engines and power plants. Carbon monoxide can lead to serious health issues, including headaches, dizziness, and confusion, and, in extreme cases, death.

Nitrogen oxides (NOx) are another group of harmful gases released during fossil fuel combustion. These include nitrogen oxide (NO) and nitrous oxide (N2O), which is also known as laughing gas. Nitrogen oxides contribute to the formation of smog, particularly on hot days, and can irritate the respiratory system, exacerbating conditions such as asthma.

Particulate matter, or particle pollution, refers to the tiny solid or liquid particles released into the air during combustion. These particles come in various sizes, with larger particles (PM10) irritating the eyes, nose, and throat, and smaller particles (PM2.5) infiltrating the deep parts of the lungs and even entering the bloodstream. The health impacts of particulate matter can be severe, particularly for vulnerable individuals.

In addition to these immediate health effects, the burning of fossil fuels releases greenhouse gases, such as carbon dioxide (CO2) and methane (CH4), which contribute to global warming and climate change. Carbon dioxide accumulates in the atmosphere, intensifying the greenhouse effect and increasing the Earth's average air temperatures. Methane is emitted during the production and transport of coal, natural gas, and oil, as well as from agricultural practices and waste decomposition.

The release of harmful chemicals and gases from fossil fuels has led to a growing awareness of the need for a transition to cleaner energy sources. While progress has been made in improving air quality in some regions, the challenges posed by climate change and increasing pollution levels globally underscore the urgency of this shift.

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Particulate matter, e.g. dust, smoke, soot, can irritate eyes and damage health

Air pollution is a complex mixture of gas-phase pollutants and particles that are released into the atmosphere due to human activities, such as burning fossil fuels and industrial production, and natural activities, such as wildfires. According to the World Health Organization (WHO), 99% of humans currently breathe polluted air, and nearly seven million deaths occur annually due to indoor and outdoor air pollution.

Particulate matter, such as dust, smoke, soot, and other tiny pieces of solids or liquids, is one of the main pollutants in the air. These particles come in various sizes, with larger particles called PM10 and smaller particles called PM2.5. PM10 is large enough to be visible and can irritate the eyes, nose, and throat. Sources of PM10 include dust from roads, farms, dry riverbeds, construction sites, and mines. PM2.5, on the other hand, is more dangerous as it can penetrate deep into the lungs and even enter the bloodstream.

Both PM10 and PM2.5 have detrimental effects on ocular health. They cause inflammation, oxidative stress, and DNA/mitochondrial damage in the eye, leading to conditions such as dry eye disease, blepharitis, conjunctivitis, and keratitis. PM can also worsen pre-existing ocular conditions, such as dry eye, allergic conjunctivitis, and infectious keratitis. In addition, PM impedes cell proliferation and migration on the ocular surface and can alter tear composition, further contributing to ocular diseases.

The impact of particulate matter on ocular health is not limited to direct exposure. Studies have shown that people commuting daily on open vehicles in highly polluted areas, such as New Delhi, India, exhibited more ocular surface symptoms than those living near their workplaces. This indicates that prolonged exposure to polluted air, even while indoors, can have adverse effects on eye health.

To mitigate the effects of particulate matter on eye health, it is essential to minimize exposure. This can be achieved by spending more time indoors, choosing outdoor activities with lower particle pollution levels, and avoiding areas with high emissions, such as busy roads and highways. Additionally, improving indoor ventilation and air quality can help reduce the impact of indoor air pollution on eye health.

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Heavy metals, e.g. mercury, lead, can cause severe health issues, especially in children

Air pollution is a pressing issue that poses severe health risks to people of all ages, with nearly seven million deaths attributed to it annually worldwide. Among the various pollutants, heavy metals, such as mercury and lead, are of significant concern due to their toxicity and ability to accumulate in the human body.

Mercury and lead are two common heavy metals found in polluted air, primarily from the combustion of gas or coal, incineration, and industrial activities. These metals have detrimental effects on overall health, especially in children, who are more vulnerable due to their developing bodies and higher air inhalation per pound of body weight.

Mercury, a potent neurotoxin, can severely damage the central nervous system. Exposure to mercury can lead to neurological issues, impacting brain development and cognitive functions in children. Even minimal exposure to mercury can result in decreased IQ and learning abilities.

Lead is another highly toxic heavy metal. Exposure to lead can cause irreversible brain damage and cognitive impairments in children, affecting their ability to learn and potentially leading to reduced IQ levels. Additionally, lead can damage children's kidneys, posing severe health risks and lifelong consequences.

The impact of heavy metals on children's health extends beyond immediate physical effects. Studies have shown a correlation between air pollution and adverse respiratory health outcomes in children, including asthma, respiratory symptoms, and deficits in lung function and growth. The developing respiratory systems of children make them more susceptible to the harmful effects of polluted air, increasing the likelihood of respiratory issues and long-term lung problems.

Furthermore, air pollution has been linked to other health concerns in children, such as vitamin D deficiency, alterations in the immune system, and even potential genetic material damage. These issues can have far-reaching consequences, impacting the well-being of current and future generations. Addressing air pollution and reducing the presence of heavy metals in the air is crucial to safeguard the health and future of our children.

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Volatile organic compounds (VOCs) contribute to smog, respiratory issues, and cancer

Volatile organic compounds (VOCs) are gases emitted into the air from products or processes. They vaporize at room temperature and are mostly released during the use of products containing them, a process known as off-gassing. VOCs play a significant role in the formation of ozone and fine particulates in the atmosphere. Under sunlight, they react with nitrogen oxides emitted from vehicles, power plants, and industrial activities to form ozone, which helps form fine particulates. This accumulation of ozone, fine particulates, and other gaseous pollutants results in smog, which reduces visibility and can irritate the eyes, nose, and throat. Smog can also worsen existing heart and respiratory problems, such as asthma, and may cause permanent damage to lung tissue.

VOCs are found in both indoor and outdoor air, with indoor concentrations up to 10 times higher. Common sources of VOCs include home cleaning products, building materials, personal care products, and outdoor sources that can enter homes. Some VOCs, such as benzene, formaldehyde, and toluene, are harmful by themselves and can cause eye, nose, skin, and throat irritation, as well as difficulty breathing, nausea, dizziness, and headaches. Long-term exposure to VOCs can damage the liver, kidneys, and central nervous system, and worsen symptoms for people with asthma and COPD.

Additionally, VOC exposure has been linked to an elevated risk of cancer, particularly lung cancer. Certain VOCs, such as benzene, formaldehyde, and polycyclic aromatic hydrocarbons (PAHs), have been extensively researched and are confirmed to have cancer-causing potential. These chemicals can be chemically converted into hazardous molecules, resulting in DNA damage, genetic alterations, oxidative stress, inflammation, and a breakdown of the cellular protective antioxidant framework, all of which contribute to the growth of cancerous cells and tumors.

To reduce exposure to VOCs, individuals can take several measures. These include buying products with less packaging, as printing materials generate VOCs, and reducing vehicle usage or opting for shared rides and public transportation. When using products containing VOCs, increasing ventilation can help lower exposure levels. Reading product labels, avoiding or limiting the use of items with harmful ingredients, and safe disposal of unwanted products are also recommended.

Governments also play a crucial role in controlling VOC emissions. Implementing measures to regulate VOC-containing products, such as aerosol consumer products, paints, and cleaning solvents, can significantly reduce VOC emissions. Additionally, improving ventilation systems in offices and schools can effectively minimize VOC levels produced by printers and copiers. These collective efforts are essential to mitigate the health risks associated with VOC exposure, including their contribution to smog and the development of respiratory issues and cancer.

Frequently asked questions

Pollutants in the air can be primary or secondary. Primary pollutants are emitted directly from a specific source, such as gases produced by vehicle combustion, industrial emissions, or forest fires. Secondary pollutants are the result of chemical reactions between primary pollutants and other atmospheric constituents under the influence of sunlight. Here are some of the common substances found in polluted air:

- Carbon dioxide (CO2)

- Carbon monoxide (CO)

- Nitrogen dioxide (NO2)

- Sulfur dioxide (SO2)

- Ozone (O3)

- Particulate matter (PM)

- Volatile Organic Compounds (VOCs)

Primary pollutants are emitted directly from a source, without undergoing any chemical transformation. Some examples include:

- Gases produced by vehicle combustion

- Industrial emissions

- Fossil fuels burned for heating or power generation

Secondary pollutants are formed when primary pollutants react with other substances in the atmosphere, often under the influence of sunlight. One example is ground-level ozone, formed when volatile organic compounds (VOCs) react with nitrogen oxides in the presence of sunlight. Secondary pollutants like ozone can irritate the eyes, nose, and throat, and have more severe health impacts on vulnerable individuals.

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