
The Clean Air Act requires the US Environmental Protection Agency (EPA) to set National Ambient Air Quality Standards (NAAQS) for six principal pollutants (criteria air pollutants) that can be harmful to public health and the environment. These pollutants are known to cause health issues, property damage, and harm to animals, crops, vegetation, and buildings. The six principal pollutants include particulate matter (PM), carbon monoxide (CO), ground-level ozone (O3), nitrogen dioxide (NO2), sulfur dioxide (SO2), and total suspended particulates (TSP). These pollutants are primarily the result of industrial activities, power plants, transportation, construction, waste burning, and other sources. Understanding and addressing these top pollutants are crucial for protecting public health and the environment.
| Characteristics | Values |
|---|---|
| Ocean pollutants | Plastic, nutrients from fertilizer runoff, nonpoint sources, light, noise, and industrial chemicals |
| Principal sources of ocean plastic pollution | Plastic bags, bottles, food containers, cutlery, wrappers, synthetic rope, and fishing items |
| Nonpoint-source pollution causes | Excess fertilizers, herbicides, insecticides, oil, grease, toxic chemicals, bacteria, nutrients from livestock, pet waste, faulty septic systems, sediment from construction sites, crop and forest lands, salt from irrigation practices, acid drainage |
| Particulate matter (PM) composition | Sulfate, nitrates, ammonia, sodium chloride, black carbon, mineral dust, water |
| Criteria air pollutants | Carbon monoxide (CO), ground-level ozone (O3), nitrogen dioxide (NO2), sulfur dioxide (SO2), particulate matter (PM), total suspended particulates (TSP) |
| Carbon monoxide characteristics | Colorless, odourless, poisonous gas, byproduct of the incomplete burning of fuels, 210 times the affinity of oxygen for haemoglobin |
| Ground-level ozone characteristics | Secondary pollutant, formed from the reaction of nitrogen oxides and volatile organic compounds in the presence of sunlight and warm temperatures, irritant to eyes and upper respiratory system |
| Nitrogen dioxide sources | Burning fossil fuels, industrial boilers, motor vehicles |
| Sulfur dioxide sources | Industrial furnaces, power plants burning coal or oil containing sulfur |
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What You'll Learn

Particulate matter (PM)
PM is commonly classified based on the size of the particles, with PM2.5 and PM10 being the most commonly referred to categories. PM2.5 refers to particles with a diameter of 2.5 micrometers or smaller, while PM10 refers to particles with a diameter of 10 micrometers or less. These particles are so small that they can be inhaled and reach deep into the lungs, and in the case of PM2.5, they may even enter the bloodstream.
Sources of PM vary and can be both indoor and outdoor. Indoor sources of PM include cooking, space heating, lighting with kerosene, tobacco smoking, burning wood or incense, and household cleaning products. Outdoor sources include traffic, transportation, industrial activities, power plants, construction sites, waste burning, and fires. It's important to note that indoor spaces can also be affected by outdoor sources, especially for smaller particles like PM2.5, which can easily enter through doors, windows, or small openings in building structures.
The health effects of particulate matter, especially PM2.5, are significant. Short-term exposures to PM10 have been linked to the worsening of respiratory diseases, including asthma and chronic obstructive pulmonary disease (COPD). Long-term exposure to PM2.5 has been associated with premature death, particularly in individuals with pre-existing heart or lung conditions. It is also linked to reduced lung function growth in children. Additionally, PM, especially PM2.5, contributes to reduced visibility, known as haze, in many parts of the world, including national parks and wilderness areas.
To protect public health, organizations like the US Environmental Protection Agency (EPA) have established standards and regulations for particulate matter pollution. The Air Quality Index (AQI) is a useful tool that helps individuals understand the air quality in their area and take appropriate actions to protect their health when PM levels are high.
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Carbon monoxide (CO)
In indoor environments, a variety of items such as unvented kerosene and gas space heaters, leaking chimneys and furnaces, and gas stoves can also release CO and impact indoor air quality. Breathing air with a high concentration of CO reduces the oxygen transported in the bloodstream to critical organs like the heart and brain. High levels of CO, which are possible indoors or in enclosed spaces, can cause dizziness, confusion, unconsciousness, and even death.
The combustion of low-grade solid fuel and biofuels in a small stove or fireplace can generate high carbon monoxide emissions. These emissions can become lethal unless the flue gases are vented outdoors through a chimney during the entire combustion process. High-grade fuels, such as natural gas, butane, or propane, typically produce less carbon monoxide when properly maintained, adequately vented, and with correct air-to-fuel ratios.
According to the US EPA, standards and data help state, tribal, and local agencies ensure that CO levels are maintained at a safe level. Additionally, the Clean Air Act requires the EPA to set National Ambient Air Quality Standards (NAAQS) for six common air pollutants, including carbon monoxide, to address health and environmental concerns.
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Ground-level ozone (O3)
Ozone is a gas composed of three oxygen atoms. It can be found in the Earth's upper atmosphere and at ground level. While stratospheric ozone is beneficial as it forms a protective layer that acts as a shield from the sun's harmful ultraviolet rays, ground-level ozone is a harmful air pollutant and a major component of smog.
Ground-level ozone is formed when two primary pollutants, nitrogen oxides (NOx) and volatile organic compounds (VOCs), react with sunlight and stagnant air. Nitrogen oxides are produced by human activities such as burning coal, gasoline, and oil in motor vehicles, homes, industries, and power plants. VOCs, on the other hand, are primarily generated by human activities like gasoline combustion, oil and gas production, residential wood combustion, and the evaporation of liquid fuels and solvents. They also originate from natural sources such as coniferous forests.
Ground-level ozone is a significant health concern. It can trigger a variety of health problems, especially for children, the elderly, and people with lung diseases like asthma. Exposure to ground-level ozone has been linked to premature mortality and an increased number of hospital admissions. It can also cause asthma attacks and other respiratory issues. The pollutant is particularly prevalent in urban environments on hot sunny days, but it can also reach high levels during the colder months and affect rural areas due to wind transportation.
In addition to its impacts on human health, ground-level ozone also affects the environment. It can damage vegetation, decrease crop productivity, and injure flowers and shrubs. Furthermore, it can harm synthetic materials, cause cracks in rubber, accelerate the fading of dyes, and contribute to the deterioration of paints and coatings. Given its adverse effects, ground-level ozone is one of the six common air pollutants identified in the Clean Air Act, and the EPA works to regulate and reduce its levels.
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Nitrogen dioxide (NO2)
The primary source of NO2 in the air is the burning of fuel, specifically from emissions produced by vehicles (such as cars, trucks, and buses), power plants, and off-road equipment. It can also be formed through photochemical reactions between nitric oxide (NO) and other air pollutants in the presence of sunlight.
Breathing air with high concentrations of NO2 can irritate the airways in the human respiratory system and aggravate respiratory diseases, especially asthma. Short-term exposure can lead to coughing, wheezing, and difficulty breathing, while longer exposures to elevated NO2 concentrations may contribute to the development of asthma and potentially increase susceptibility to respiratory infections.
To address the health risks associated with NO2 pollution, organizations like the US Environmental Protection Agency (EPA) and the California Air Resources Board have implemented measures to reduce emissions and improve air quality. These efforts include setting standards, such as the National Ambient Air Quality Standard (NAAQS), and working with state, local, and tribal governments to develop plans for reducing NO2 levels in areas that do not meet the established standards.
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Sulfur dioxide (SO2)
SO2 is one of a group of highly reactive gases known as "oxides of sulfur" or sulfur oxides (SOx). These gases can react with other compounds in the atmosphere to form small particles, contributing to particulate matter (PM) pollution. These particles can penetrate deeply into the lungs and cause a range of respiratory issues, especially during physical activity. Long-term exposure to high levels of SO2 can increase respiratory symptoms and reduce lung function.
SO2 emissions can lead to high concentrations of SO2 in the air, which, in turn, can contribute to the formation of other sulfur oxides. These sulfur oxides can have further detrimental effects on the environment. For example, SOx gases can react with other atmospheric compounds to form fine particles that reduce visibility (haze) in various areas, including national parks. Additionally, these particles can stain and damage stone and other materials, including culturally significant objects.
Furthermore, sulfur dioxide and other sulfur oxides can contribute to acid rain, which can harm sensitive ecosystems. While SO2 levels have improved over time due to policies promoting cleaner fuels and pollution controls on power plants, it remains a health concern. High levels of SO2 exposure can cause wheezing, shortness of breath, chest tightness, and other respiratory issues, particularly in individuals with asthma.
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