Helena Joyce
Open-top tanks, along with other types of tanks, can emit pollutants that pose a threat to human health and the environment. The primary pollutant of concern is often volatile organic compounds (VOCs), which can be found in tanks holding heavy fuels. These emissions are typically calculated using mathematical formulas or estimated by companies, rather than directly measured. Inaccurate estimations can lead to underreporting or overestimating emissions, impacting the effectiveness of pollution control and regulation. To address this, various strategies for tank emissions management are implemented, such as installing internal floating roofs and seals or using technologies like carbon absorption canisters. Accurate estimation and control of emissions are crucial for maintaining air quality, complying with regulations, and mitigating environmental and health risks.
| Characteristics | Values |
|---|---|
| Pollutants | VOCs, No. 6 fuel oil, asphalt, hazardous chemicals, speciated organic compounds |
| Emission Calculation | Equations and algorithms in Chapter 7 of AP-42, mathematical formula written by the oil industry |
| Emission Control Methods | Installing internal floating roofs and seals, increasing vent set pressure, using carbon absorption canisters |
| Regulatory Bodies | EPA, Minnesota Pollution Control Agency, US Environmental Protection Agency |
| Related Issues | Underestimation of emissions, lack of direct testing, self-reporting by companies, potential groundwater contamination |
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What You'll Learn
VOCs and HAPs are emitted from open tanks
Volatile organic compounds (VOCs) and hazardous air pollutants (HAPs) are emitted from open tanks. These emissions can have a significant impact on air quality and human health. While other organic compounds may be hazardous, VOCs are considered the primary pollutant of concern. VOCs are emitted as gases from certain solids or liquids and include a range of chemicals, some of which can have adverse health effects. The continuous increase in refined oil consumption has led to a significant rise in VOC emissions during oil storage, transportation, and marketing.
Internal floating-roof tanks, for instance, are widely used to store light oil products, and the evaporation area of the stored liquids can be significantly reduced due to the floating deck arrangement. However, the long-term usage of these tanks can lead to a decrease in the rim seal's elasticity, widening the rim seal gap. This results in increased evaporation and diffusion of oil vapors from tank vents into the atmosphere.
To minimize evaporation and reduce VOC emissions, several control methods can be implemented. For instance, installing an internal floating roof and seals can reduce evaporation by up to 99%. Additionally, increasing the vent set pressure for fixed-roof tanks may eliminate routine emissions if the pressure is higher than the vapor space pressure during regular tank operation.
HAP emissions from upstream production operations are also important to consider due to their potential impact on regional ozone levels and nearby populations. HAPs, along with VOCs, are emitted from open tanks in oil and natural gas production, even when control measures are in place. These emissions can be highly variable and pose a significant risk to human health and the environment.
It is worth noting that the underestimation of emissions from open tanks is a common issue. Companies often rely on equations developed by the petroleum industry instead of directly measuring emissions, which can lead to inaccurate reporting. This highlights the importance of accurate emission estimations and the need for direct measurement methods to ensure the effectiveness of emission control and mitigation strategies.
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Calculating emissions from open tanks
Identify Tank Characteristics
First, it is essential to identify the characteristics of the tank in question. This includes factors such as the type of tank (fixed-roof, floating roof, internal floating roof, etc.), the physical and chemical characteristics of the stored liquid, and the operating conditions. For instance, hot and heated tanks have different emission considerations compared to tanks at constant temperatures.
Determine the Relevant Equations
The American Petroleum Institute (API) and the US Environmental Protection Agency (EPA) have developed various equations and software to estimate emissions from different types of tanks. The widely accepted gold standard for tank emissions calculations is the AP-42 Chapter 7 guidelines, which cover a range of scenarios, including different tank shapes, vapour pressures, and Volatile Organic Compound (VOC) content. The specific equations to use will depend on the tank characteristics identified in the previous step.
Collect Data
To apply the equations, relevant data must be collected. This includes variables such as tank diameter, liquid temperature, wind velocity, liquid chemical composition, and historical usage data. Continuous emission monitoring systems are the preferred method for data collection, but they may not always be available or accurate.
Perform Calculations
Using the selected equations and collected data, perform the necessary calculations to estimate the emissions from the open tank. The calculations will vary depending on the specific guidelines and software used. For example, the EPA's TANKS software has versions 4.09D, 5.0, and 5.1, each with slightly different functionalities and requirements.
Report and Manage Emissions
Finally, the calculated emissions should be reported and managed to ensure compliance with relevant regulations, such as the Clean Air Act Amendments of 1990 and the Emergency Planning and Community Right-to-Know Act of 1986. This may involve implementing strategies to reduce emissions, such as improving insulation to minimise breathing losses or using software solutions to track and manage emissions data.
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Regulations for open tank emissions
Open-top tanks are used to store fuel and chemicals in many industries, from adhesive manufacturers to aerospace manufacturers. The volatility of the stored liquid and regular tank usage can result in emissions, which often contain volatile organic compounds (VOCs) that pose a threat to human health and the environment.
In the United States, the Environmental Protection Agency (EPA) has established regulations to control and reduce emissions from storage tanks. These regulations vary depending on the type of tank and the liquids being stored. For example, Rule 463 applies to storage tanks with a design capacity exceeding 19,815 gallons or those within the range of 251 to 19,815 gallons designed for gasoline storage. The rule mandates floating roofs with seals or fixed roofs with 95% emission control for larger tanks storing organic liquids with a true vapor pressure (TVP) above a certain threshold.
Additionally, the EPA has published the Limited Approval, Limited Disapproval of the California Air Plan Revisions, which addresses the use of reasonably available control technology (RACT) for ozone National Ambient Air Quality Standards (NAAQS) for tanks. The EPA has rejected certain demonstrations of RACT by the California Air Resources Board (CARB) due to deficiencies in aligning with the EPA's Oil and Gas Control Techniques Guidelines (CTG).
To comply with regulations, companies must accurately estimate and manage their tank emissions. This involves using emission factors, inventories, and calculations based on API Tank equations, AP-42 chapter 7, and scientific research. Continuous emission monitoring is preferred, but when direct measurement is not possible, the API's formulated methodologies help calculate emissions.
Furthermore, emission control methods depend on the tank type and stored liquid. For instance, installing internal floating roofs and seals can reduce evaporation from fixed-roof tanks, with control efficiencies ranging from 60 to 99%. Increasing the vent set pressure for these tanks may also eliminate routine emissions if it exceeds the pressure in the vapor space during regular operation.
Overall, by adhering to EPA regulations, accurately estimating emissions, and implementing control strategies, companies can minimize air pollution and mitigate the health and environmental risks associated with open-tank emissions.
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Controlling emissions from open tanks
Open tanks emit volatile organic compounds (VOCs), which are considered the primary pollutant of concern. VOCs can pose a threat to human health and contribute to climate change. To control emissions from open tanks, several strategies can be employed:
Accurate Estimation and Monitoring of Emissions:
- Accurate estimation of emissions is crucial for effective control. This involves using reliable methodologies, such as emission factors, and continuous monitoring systems to determine the quantity and composition of emissions.
- The American Petroleum Institute (API) has conducted extensive studies and formulated equations to estimate emissions. However, there have been concerns about the accuracy of these equations, with some companies underreporting their emissions.
- Continuous emission monitors are preferred for data collection, but direct measurement of emissions from certain sources can be challenging.
Tank Design and Modification:
- The design and type of tank significantly impact emission levels. For fixed-roof tanks, installing internal floating roofs and seals can reduce evaporation and control emissions with an efficiency of 60-99%, depending on the specific setup.
- Increasing the vent set pressure in fixed-roof tanks may eliminate routine emissions if it exceeds the pressure in the vapor space during normal operation.
- Secondary seals can provide additional control over evaporative losses.
- Specific requirements for tank fittings and seals are outlined in regulations, such as Chapter 115 of the Texas Administrative Code.
Vapor Collection and Control:
- Vapor collection systems, such as bladder tanks, with pressure measurement instrumentation, can effectively capture vapors during loading, unloading, and storage.
- Regenerative thermal oxidizers can be used to replace outdated open flare technology, providing a more efficient and flexible solution for handling high-concentration vapors.
- Thermal oxidation is a widely used air pollution control technology that converts unwanted organic compounds into carbon dioxide and water through high-temperature oxidation.
Compliance and Emission Reduction Strategies:
- Understanding emission regulations and permitting requirements is essential. Accurate emission estimations help determine applicable permits and develop emission reduction strategies.
- Federal organizations, such as the EPA, use emission data to plan and implement emissions reduction programs.
- Companies may be required to install special equipment, such as carbon absorption canisters, to control emissions and mitigate their impact on public health.
By combining accurate emission estimation, strategic tank design, effective vapor control, and compliance with regulations, emissions from open tanks can be significantly reduced, minimizing their impact on the environment and human health.
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Impact of open tank emissions on groundwater
Open-top tanks emit various pollutants, including volatile organic compounds (VOCs) and other hazardous chemicals. These emissions can have a significant impact on groundwater, a crucial source of drinking water for nearly half of all Americans.
The primary pollutant of concern from open-top tanks is VOCs. VOCs are organic compounds that have a high vapour pressure and can easily become gases. They are commonly found in petroleum products and have a range of negative health effects. VOCs can pose a threat to human health, with levels sometimes reaching concentrations that violate federal clean air standards. Additionally, VOCs can combine with other pollutants to form ozone, a greenhouse gas contributing to climate change.
To manage tank emissions, it is essential to implement control methods to minimise air pollution. These methods vary depending on the tank type and the liquids stored. For instance, installing an internal floating roof and seals in a fixed-roof tank can reduce evaporation and control emissions with an efficiency of 60 to 99 per cent. Increasing the vent set pressure in fixed-roof tanks is another strategy to eliminate routine emissions.
However, the impact of open-top tank emissions on groundwater goes beyond air pollution. Underground storage tanks (USTs) are commonly used to store gasoline, heating oil, and other liquid petroleum products. If these tanks leak, the petroleum vapours can enter buildings and pose a risk to human health, a problem known as Petroleum Vapor Intrusion (PVI). Leaking USTs can also contaminate groundwater, leading to serious environmental and health risks.
The US Environmental Protection Agency (EPA) is actively researching and developing tools to address these issues. They are working to identify vulnerabilities to groundwater from leaking USTs and create a groundwater vulnerability model at local, regional, and national scales. This will assist in triage site cleanups and assessing the potential cumulative impacts on groundwater supplies.
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Frequently asked questions
The primary pollutant of concern is VOCs (volatile organic compounds).
Emissions from open tanks are calculated using equations and algorithms from Chapter 7 of AP-42.
The calculations of emissions from open tanks vary depending on the tank type and the liquid stored. For example, for fixed roof tanks, emissions from standing loss, working loss, and total loss for each pollutant must be considered.
Yes, the emissions from open tanks can pose a threat to human health. VOCs can reach levels that violate federal clean air standards, and they can also combine with other pollutants to form ozone, a greenhouse gas contributing to climate change.
